Cyclizative Atmospheric CO₂ Fixation by Unsaturated Amines with <i>t</i>-BuOI Leading to Cyclic Carbamates

Abstract

A cyclizative atmospheric CO(2) fixation by unsaturated amines such as allyl and propargyl amines under mild reaction conditions, efficiently leading to cyclic carbamates bearing a iodomethyl group, have been developed utilizing tert-butyl hypoiodite (t-BuOI).