Publication | Closed Access
Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO<sub>2</sub>
192
Citations
42
References
2014
Year
Cross-coupling ReactionEngineeringCatalytic SynthesisOrganic ChemistryOrganometallic CatalysisCatalysisMolecular CatalysisChemistryAllyl EstersExquisite Selectivity ProfileAsymmetric CatalysisBiomolecular EngineeringLigand Backbone
A novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO2 has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.
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