Chiral Amplification in One-Dimensional Helical Nanostructures Self-Organized from Phenylethynyl Thiophene with Elaborated Long-Chain Dicarboxamides

Abstract

A bis-phenylethynyl thiophene derivative functionalized with long-chain pyridyl biscarboxamides displayed unique helical morphology in the xerogel form via nicely complementary intermolecular interactions. The helical nanostructures visualized by TEM and AFM remarkably matched well with the computational results. Supramolecular chirality can be amplified by coassembly of a chiral conductor to bias the helical arrangement.