High Energy Efficiency Plasma Conversion of CO₂at Atmospheric Pressure Using a Direct-Coupled Microwave Plasma System

Abstract

Energy and conversion efficiencies of the carbon dioxide (CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> ) dissociation process at atmospheric-pressure conditions are investigated using a direct-coupled continuous microwave plasma system (MPS). Gas chromatography and mass spectrometer measurements were performed on the gas mixture postplasma treatment, over a range of specific energy inputs (SEIs) (0.06–0.6 eV mol <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$^{-1})$ </tex-math></inline-formula> , in order to determine species mass fractions of CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> , carbon monoxide, and oxygen. In this region of SEI, energy efficiency is maximized at the cost of conversion efficiency. The corresponding maximum observed quantities for conversion efficiency and energy conversion efficiency (ECE) occurred at conditions close to the end of the test range and are, respectively, 9% and 0.0048 L min <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$^{-1}\text{W}^{-1}$ </tex-math></inline-formula> . The maximum throughput of CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> converted was 0.59 L min <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$^{-1}$ </tex-math></inline-formula> , at an SEI of 0.1 eV mol <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$^{-1}$ </tex-math></inline-formula> and an ECE of 0.004 L min <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$^{-1}\text{W}^{-1}$ </tex-math></inline-formula> . Optical emission spectroscopy was used to approximate the rotational and vibrational temperatures of the plasma system to be in the range of 7000–8000 K. This paper suggests that an MPS is the most energy efficient method in dissociating CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> under atmospheric pressure and, therefore, most suitable to be used in a CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> recycling setup, which can further increase conversion rates.