Imaging the O(¹D) + CD₄ → OD + CD₃ Reaction Dynamics: The Threshold of Abstraction Pathway

Abstract

The O((1)D) + CD4 → OD + CD3 reaction was investigated using the crossed molecular beam technique with sliced velocity map imaging at four different collision energies: 1.6, 2.8, 4.6, and 6.8 kcal/mol. The vibrational ground state product CD3 was detected using a (2 + 1) resonance-enhanced multiphoton ionization (REMPI). Remarkably different features were found in the forward and backward scatterings, and gradually changed with the collision energy. These features were attributed to two distinctive reaction mechanisms-insertion and abstraction-that occur on the ground and excited state surfaces, respectively. Contributions from the two mechanisms were extracted from the experiment results, and a positive correlation was found between the abstraction proportion and the collision energy. The threshold for the abstraction pathway was determined and compared with results from calculations.