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Total Synthesis of (-)-Pyrenophorol
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2012
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Intermolecular Mitsunobu CyclizationChemical EngineeringEfficient Synthetic RouteEngineeringAlkene MetathesisTotal SynthesisOrganic ChemistryCatalysisChemistryHeterocycle ChemistrySynthetic ChemistrySharpless Asymmetric Epoxidation
An efficient synthetic route has been developed for the synthesis of (-)-pyrenophorol employing Sharpless asymmetric epoxidation, olefin cross-metathesis, and intermolecular Mitsunobu cyclization.