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The influence of pressure on the infrared spectra of hydrogen-bonded solids. IV. Miscellaneous compounds
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1976
Year
EngineeringHydrogen EmbrittlementChemistrySpectroscopic PropertySpectra-structure CorrelationGeneral RuleMiscellaneous CompoundsHydrogen-bonded SolidsBiophysicsMaterials ScienceChemical BondInfrared SpectroscopyPhysical ChemistrySolid MechanicsSolid CompoundsHydrogenInfrared SpectraNatural SciencesSpectroscopyHydrogen BondsHydrogen BondHydrogen-bonded LiquidMechanics Of Materials
Measurements have been made of the influence of pressure on the stretching and bending frequencies of hydrogen bonds in a further series of 15 solid compounds. Two exceptions have been found tothe general rule that an increase of pressure decreases the X-H stretching frequencies of weak and medium-strength X-H....Y bonds. Possible explanations are offered of the exceptions.