Enhanced emission and photoconductivity due to photo-induced charge transfer from Au nanoislands to ZnO

Shang-Hsuan Wu, Ching‐Hsiang Chan, Ching-Hang Chien, Mohammad Tariq Yaseen, Ching-Tarng Liang, Yia‐Chung Chang

Applied Physics Letters · 2016 · 10 citations · 24 references

Concepts

Abstract

We report systematic studies based on photoluminescence, Hall, and photoconductivity measurements together with theoretical modeling in order to identify mechanisms for the photo-induced charge transfer effects in ZnO thin film incorporated with the Au nano-islands (AuNIs). Significant enhancement of near band edge emission and improvement in conductivity of ZnO/AuNIs samples after illumination are observed, which are attributed to the photo-induced hot electrons in Au which are then transferred into the conduction band of ZnO as long as the excitation energy is higher than the offset between the ZnO conduction-band minimum and Au Fermi level. Our experimental results are consistent with the general features predicted by first principles calculations.

References

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