Enhancing the Kinetics of Li‐Rich Cathode Materials through the Pinning Effects of Gradient Surface Na<sup>+</sup> Doping

Renpeng Qing, Ji‐Lei Shi, Dongdong Xiao, Xu‐Dong Zhang, Ya‐Xia Yin, Yunbo Zhai, Lin Gu, Yu‐Guo Guo

Advanced Energy Materials · 2015 · 380 citations · 32 references

DOIFull text

Open access

Concepts

Abstract

Gradient surface Na-ion doping is realized and demonstrated as an effective strategy to enhance the kinetics of Li-rich cathode materials. Owing to the pinning effect of Na-doping in the Li layer, the resultant Li-rich particles exhibit superior electrochemical performances in terms of specific capacity, Coulombic efficiency, and cycling stability. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

32