Concepedia

Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

Kohei Harada, Marina Nogami, Keiichi Hirano, Daisuke Kurauchi, Hisano Kato, Kazunori Miyamoto, Tatsuo Saito, Masanobu Uchiyama

Organic Chemistry Frontiers · 2016 · 34 citations · 33 references

DOI

Concepts

Abstract

A novel method for the preparation of diverse allylic boronates from simple allylic alcohols is reported.

References

33

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Diastereo- and enantioselective aldehyde addition reactions of 2-allyl-1,3,2-dioxaborolane-4,5-dicarboxylic esters, a useful class of tartrate ester modified allylboronates

William Roush, Alan E. Walts, Lee K. Hoong · Journal of the American Chemical Society · 1985 · 308 citations

, , +5

Transition‐Metal‐Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

Amadeu Bonet, Cristina Pubill‐Ulldemolins, Carles Bó et al. · Angewandte Chemie International Edition · 2011 · 299 citations · Full text

, , +10

Recent Advances in the Activation of Boron and Silicon Reagents for Stereocontrolled Allylation Reactions

Jason W. J. Kennedy, Dennis G. Hall · Angewandte Chemie International Edition · 2003 · 284 citations · Full text

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