RSC Advances · 2016 · 66 citations · 29 references
Natural SciencesMaterials ScienceCrystal StructureSpectroscopyCrystal Field TheoryEmission SpectroscopyFine StructurePhosphorescence SpectroscopyAnisotropic ExpansionEmission Spectra AnalysisGarnet MineralogyPhosphor MaterialsPhosphorescent MaterialsPhosphorsStokes ShiftYttrium Aluminum Garnet Hosts
An overall compression with anisotropic expansion of the Ce<sup>3+</sup> local environment resulted from incorporating Mg<sup>2+</sup> into the Y<sup>3+</sup> site. Insight into the crystal field splitting and the Stokes shift is given to interpret the Ce<sup>3+</sup> emission redshift.
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