Synthesis of stereodiblock polyisoprene consisting of cis-1,4 and trans-1,4 sequences by using a neodymium catalyst: change of the stereospecificity triggered by an aluminum compound

Ryō Tanaka, Yuuya Kaede, Hiroki Sato, Peter Eberhardt, Yuushou Nakayama, Takeshi Shiono

Polymer Chemistry · 2016 · 42 citations · 27 references

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Abstract

The synthesis of stereodiblock polyisoprene which consists of<italic>cis</italic>-1,4 and<italic>trans</italic>-1,4 sequences was achieved by using a neodymium catalyst.

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