Concepedia

A pendant proton shuttle on [Fe<sub>4</sub>N(CO)<sub>12</sub>]<sup>−</sup>alters product selectivity in formate vs. H<sub>2</sub>production via the hydride [H–Fe<sub>4</sub>N(CO)<sub>12</sub>]<sup>−</sup>

Natalia D. Loewen, Emily J. Thompson, M. S. Kagan, Carolina L. Banales, Thomas W. Myers, James C. Fettinger, Louise A. Berben

Chemical Science · 2016 · 76 citations · 40 references

DOIFull text

Open access

Concepts

Abstract

A proton shuttle in the second coordination sphere of [Fe<sub>4</sub>N(CO)<sub>12</sub>]<sup>−</sup>promotes H<sub>2</sub>evolution over formate formation from CO<sub>2</sub>.

References

40

<i>International Tables for X-ray Crystallography</i>

Acta Crystallographica Section B · 1976 · 14.2K citations · Full text

, , +11

Electrochemical Methods: Fundamentals and Applications

Dr M.R. de Rooij · Anti-Corrosion Methods and Materials · 2003 · 13.2K citations

, , +12

Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.

Richard S. Nicholson, Irving. Shain · Analytical Chemistry · 1964 · 5.1K citations

, , +14

A Local Proton Source Enhances CO <sub>2</sub> Electroreduction to CO by a Molecular Fe Catalyst

Cyrille Costentin, Samuel Drouet, Marc Robert et al. · Science · 2012 · 1.3K citations

, , +16

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s <sup>−1</sup> for H <sub>2</sub> Production

Monte L. Helm, Michael Stewart, R. Morris Bullock et al. · Science · 2011 · 1.2K citations · Full text

, , +17