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The [B<sub>3</sub>(NN)<sub>3</sub>]<sup>+</sup> and [B<sub>3</sub>(CO)<sub>3</sub>]<sup>+</sup> Complexes Featuring the Smallest π‐Aromatic Species B<sub>3</sub><sup>+</sup>
79
Citations
31
References
2016
Year
Inorganic ChemistrySpectroscopic IdentificationPhysicsBiochemistryNatural SciencesCoordination ComplexMolecular ComplexQuantum ChemistryChemistryMolecular ChemistrySpectra-structure CorrelationInorganic Compound
We report the spectroscopic identification of the [B3 (NN)3](+) and [B3 (CO)3](+) complexes, which feature the smallest π-aromatic system B3 (+). A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B3 L2 ](+) σ-donation.
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