Interaction of a Self-Assembled Ionic Liquid Layer with Graphite(0001): A Combined Experimental and Theoretical Study

Abstract

The interaction between (sub)monolayers of the ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide [BMP](+)[TFSA](-) and graphite(0001), which serves as a model for the anode|electolyte interface in Li-ion batteries, was investigated under ultrahigh vacuum conditions in a combined experimental and theoretical approach. High-resolution scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and dispersion-corrected density functional theory (DFT-D) calculations were employed. After vapor deposition at 300 K, XPS indicates molecular adsorbates with a 1:1 ratio of cations/anions. Cool down to ∼100 K leads to the formation of an ordered (2D) crystalline phase, which coexists with a mobile (2D) liquid. DFT-D calculations reveal that adsorbed [BMP](+) and [TFSA](-) species are arranged alternately in a row-like adsorption structure (cation-anion-cation-anion) and that adsorption is dominated by dispersion interactions between adlayer and substrate, on the one hand, and electrostatic interactions between the ions in a row, on the other hand. Simulated STM images of that structure closely resemble the experimental molecular resolved STM images and show that the resolved features mostly stem from the cations.