Concepedia

A [3Fe–3S]<sup>3+</sup>cluster with exclusively μ-sulfide donors

Yousoon Lee, Ie‐Rang Jeon, Khalil A. Abboud, Ricardo García‐Serres, Jason Shearer, Leslie J. Murray

Chemical Communications · 2015 · 32 citations · 48 references

DOI

Concepts

Abstract

A [3Fe-3(μ-S)](3+) cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy.

References

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