Chemical Science · 2013 · 720 citations · 131 references
EngineeringChemical EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryEnergy MaterialsElectrochemical CellsElectrochemical Energy ConversionElectrochemical Energy StorageElectrode MaterialsElectrolysis ProcessesRedox-active MaterialsElectrocatalystsElectrocatalytic Oxygen EvolutionHydrogen EvolutionHydrogen Evolution CatalystsHydrogen Evolution ReactionNickel AlloysNickel-based AlloysOxygen Evolution Reaction
Splitting water to hydrogen and oxygen is a promising approach for storing energy from intermittent renewables, such as solar power. Efficient, scalable solar-driven electrolysis devices require active electrocatalysts made from earth-abundant elements. In this mini-review, we discuss recent investigations of homogeneous and heterogeneous hydrogen evolution electrocatalysts, with emphasis on our own work on cobalt and iron complexes and nickel-molybdenum alloys.
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Trends in the Exchange Current for Hydrogen Evolution
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