Publication | Closed Access
Thiourea‐Catalyzed Enantioselective Fluorination of β‐Keto Esters
61
Citations
71
References
2012
Year
β‐Keto EstersNovel OrganocatalystsEnantioselective SynthesisEngineeringEnantioselective FluorinationsFluorination ReagentFluorous SynthesisOrganic ChemistryCatalysisChemistryAsymmetric CatalysisN ‐FluorobisbenzenesulphonimideBiomolecular Engineering
Abstract Bifunctional chiral thioureas have been successfully used as organocatalysts in enantioselective fluorinations of β‐keto esters. The corresponding products could be obtained with good to excellent enantioselectivity in high yields by using N ‐fluorobisbenzenesulphonimide (NFSI) as fluorination reagent.
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