Energy & Environmental Science · 2011 · 68 citations · 23 references
Natural SciencesMaterials EngineeringMaterials ScienceEnergy MaterialsMaterials ChemistryNanomaterialsNanostructured Energy MaterialsNanotubesPhotoelectrochemical MaterialsPhotovoltaic MaterialsSolar Cell MaterialsSolar CellsDye-sensitized Solar CellsFlexible Solar CellsFlexible SubstratesNanostructured Solar CellsNanotube FunctionalizationNanotube Growth MechanismsPolyethylene TerephthalateSolar Cell Fabrication
The growth of TiO2 nanotube arrays on plastic flexible substrates is researched. The approach uses anodization of a titanium thick film for obtaining nanotubes directly on poly(ethylene terephthalate) (PET) and Kapton HN substrate. The morphological features of the tubes can be finely tuned by varying the preparation conditions, and tube morphology affects the functional properties of the nanotube array. Crystallization of the anatase phase in nanotubes on Kapton HN substrate is obtained via post growth annealing. The nanotube arrays have been dye-sensitized using the commercial Ru-based N719 dye. The system was tested as photoanode in a flexible dye sensitized solar cell. Photoconversion efficiency of 3.5% was obtained.
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Smooth Anodic TiO<sub>2</sub> Nanotubes
Jan M. Macák, Hiroaki Tsuchiya, Luciano Taveira et al. · Angewandte Chemie International Edition · 2005 · 871 citations · Full text