Publication | Closed Access
Characterization of Reactive Intermediates by Diffusion-Ordered NMR Spectroscopy: A Snapshot of the Reaction of 13CO2 with [Cp2Zr(Cl)H]
86
Citations
18
References
2002
Year
EngineeringNew ToolMagnetic ResonanceMolecular BiologyOrganic ChemistryChemistrySpectra-structure CorrelationElectron Paramagnetic ResonanceReaction IntermediateInorganic ChemistryBiochemistryReactivity (Chemistry)Coordination ComplexNatural SciencesReactive IntermediatesDiffusion-ordered Nmr SpectroscopyDosy Nmr SpectroscopyMolecular ComplexReaction IntermediatesNuclear Magnetic Resonance Spectroscopy
A new tool for the investigation of reaction intermediates: By using DOSY NMR spectroscopy, the presence of a binuclear complex 1 as the key intermediate on the way to 2 (see spectrum) was detected for the first time in the title reaction.
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