Physical Review Letters · 2004 · 12 citations · 5 references
EngineeringChemical EngineeringChemical KineticsStochastic ProcessesTransport PhenomenaDiffusion ProcessesKinetic ModelingPorous MaterialsReaction-diffusion SystemsStochastic Differential EquationsTransport In Porous MediaConcentrationEffective Diffusion CoefficientMean-field ApproximationPorosityPorosity DistributionPorous MediaReaction-diffusion EquationsReaction-diffusion Phenomena
We study the effects of quenched porosity fluctuations in the presence of nonlinear kinetics in a reaction-diffusion porous system. Adopting a weak-noise approximation and a mean-field assumption, a renormalized equation of motion for the average concentration of a chemical species is obtained. It is characterized by a smaller effective diffusion coefficient and by the presence of supplementary nonlinear reactive terms. Explicit results are given for a Gaussian porosity distribution and for a long-ranged one. Comparisons with simulations in one dimension are presented.
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