First Heterotrimetallic {3 d‐4 d‐4 f} Single Chain Magnet, Constructed from Anisotropic High‐Spin Heterometallic Nodes and Paramagnetic Spacers

Abstract

Three in one: Heterotrimetallic 1D coordination polymers are designed by assembling heteronuclear nodes (see figure), {Cu2Ln}, with paramagnetic octacyanido-metallates, [M(CN)8]3− (M=Mo, W), acting as spacers. By choosing a strongly anisotropic lanthanide (DyIII), a new single chain magnet is obtained.