Journal of the American Chemical Society · 2003 · 806 citations · 10 references
Natural SciencesChemistryMaterials ScienceCrystal StructureMagnetic MaterialsMolecular PhysicsMagnetic Properties Of SolidsMagnetism Of Inorganic CompoundsMolecular SymmetryNuclear SpinCoordination Compound MagnetismHigh-spin StatesMagnetic Properties Of Transition Metal ComplexesMolecular MagnetismMolecular MagnetsPolynuclear ComplexesSingle-molecule MagnetismSingle-molecule Magnets
We report now the first single molecule magnet (SMM) consisting of d-f elements. The present study demonstrates that the synthesis of the d-f polynuclear molecule is a very promising approach to SMMs. (1) The d-f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component.
10
Magnetic bistability in a metal-ion cluster
Roberta Sessoli, Dante Gatteschi, Andréa Caneschi et al. · Nature · 1993 · 4.3K citations
Natural Sciences, Chemistry, Physics +14
Correlations between climate records from North Atlantic sediments and Greenland ice
Gérard C. Bond, Wallace S. Broecker, S. J. Johnsen et al. · Nature · 1993 · 2.4K citations
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
Roberta Sessoli, Hui Lien Tsai, Ann R. Schake et al. · Journal of the American Chemical Society · 1993 · 2.3K citations
Natural Sciences, Chemistry, Physics +11
Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets
F. Lionti, R. Ballou, Dante Gatteschi et al. · Nature · 1996 · 2K citations
Large Clusters of Metal Ions: The Transition from Molecular to Bulk Magnets
Dante Gatteschi, Andréa Caneschi, Luca Pardi et al. · Science · 1994 · 842 citations