Effect of Surface‐Active Substances on the Rheological Properties of Silicon Carbide Suspensions in Paraffin

Abstract

In this paper, the possibility of stabilization of SiC suspensions in paraffin (hot‐molding slips) was investigated from the colloid science point of view. By considering the surface properties of finely dispersed silicon carbide, surface‐active agents (fatty amine and alkylsuccinimide) which are suitable for surface modification by chemical adsorption on SiC were selected. Adsorption of fatty amines and alkylsuccinimide was carried out in model experiments in chloroform. Increasing the length of the carbon–hydrogen chain caused the adsorption to decrease, and the adsorption area of one molecule in the saturated adsorption layer to increase. The stabilizing effect of surface‐active agents resulted in improved flow behavior of hot‐molding slips. The efficiency of surface‐active agents increased with increased adsorption layer thickness. In highly concentrated SiC hot‐molding slips, a combination of alkylsuccinimide and fatty amine proved to be very efficient. This synergistic effect of long‐ and short‐chained surface‐active agents is discussed in terms of an adsorption layer model.