Publication | Closed Access
A novel, facile route to β-fluoroamines by hydrofluorination using superacid HF–SbF5
70
Citations
26
References
2007
Year
EngineeringFacile RouteBeta-fluoro Nitrogen AnaloguesFluorous SynthesisOrganic ChemistryReactive Electrophilic IntermediatesSuperacid Hf–sbf5ChemistrySuperacid Hf-sbfHalogenationBiomolecular Engineering
A range of unsaturated amines and sulfonamides were converted to beta-fluoro nitrogen analogues after hydrofluorination in superacid HF-SbF(5), based on the formation of highly reactive electrophilic intermediates.
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