Concepedia

Diastereoselective allylation and crotylation of N-unsubstituted imines derived from ketones

Bhartesh Dhudshia, Jorge Tiburcio, Avinash N. Thadani

Chemical Communications · 2005 · 65 citations · 27 references

DOI

Concepts

Abstract

A wide variety of tertiary carbinamines are synthesized in high yields via diastereoselective allylation and crotylation of in situ generated N-unsubstituted ketimines.

References

27

A General Catalytic Allylation Using Allyltrimethoxysilane

Shingo Yamasaki, Kunihiko Fujii, Reiko Wada et al. · Journal of the American Chemical Society · 2002 · 224 citations

, , +6

Catalytic Asymmetric Allylation of Imines via Chiral Bis-π-allylpalladium Complexes

Hiroyuki Nakamura, Kaori Nakamura, Yoshinori Yamamoto · Journal of the American Chemical Society · 1998 · 196 citations

, , +8

Asymmetric Allylboration of Aldehydes and Ketones Using 3,3‘-Disubstitutedbinaphthol-Modified Boronates

T. Robert Wu, Lixin Shen, J. Michael Chong · Organic Letters · 2004 · 173 citations

, , +9

Stereospecific, Enantioselective Allylation of α‐Hydrazono Esters by Using Allyltrichlorosilanes with BINAP Dioxides as Neutral‐Coordinate Organocatalysts

Chikako Ogawa, Masaharu Sugiura, Shū Kobayashi · Angewandte Chemie International Edition · 2004 · 136 citations

, , +8

α-Aminoallylation of Aldehydes with Ammonia:  Stereoselective Synthesis of Homoallylic Primary Amines

Masaharu Sugiura, Keiichi Hirano, Shū Kobayashi · Journal of the American Chemical Society · 2004 · 135 citations

, , +7