Publication | Closed Access
A Dynamically Inverting π‐Bowl Complex
83
Citations
34
References
2009
Year
Quantum ScienceInorganic ChemistryDynamic Inversion BehaviourEngineeringPhysicsBowl-to-bowl InversionNatural SciencesTheoretical Inorganic ChemistryCoordination ComplexNumerical SimulationPhysical ChemistryMolecular ComplexSuper BowlChemistryTheta FunctionComplex DynamicBiophysics
The super bowl: The dynamic inversion behaviour of [CpRu(η6-sumanene)]PF6 (see picture; sumanene=C21H12) was investigated in solution by NMR studies. This result, the first elucidation of bowl-to-bowl inversion in π-bowl transition metal complexes, is solvent- and temperature-dependent.
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