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A cyano-bridged single-chain magnet featuring alternate high- and low-spin manganese(iii) porphyrins
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Citations
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References
2013
Year
Magnetic PropertiesLow-spin ManganeseEngineeringMagnetic ResonanceChemistryMagnetoresistanceSingle-chain MagnetMagnetismAdjacent MnCyano-bridged Single-chain MagnetBiophysicsMaterials ScienceInorganic ChemistryPhysicsDemonstrate Perfect LinearityPhysical ChemistryMagnetic MaterialSpintronicsFerromagnetismMolecule-based MagnetNatural SciencesCoordination ComplexMolecular ComplexMetal Chain Compound
The chains in complex [Mn(TPP)][Mn(TPP)(CN)2] (H2TPP = meso-tetra(4-phenyl)-porphyrin) demonstrate perfect linearity, and are well isolated with the nearest interchain Mn-Mn separation of 12.95 Å. Ferromagnetic coupling is present among adjacent Mn(III) ions, and single-chain magnet (SCM) behaviour is verified.
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