Visible‐Light‐Induced H<sub>2</sub> Evolution from an Aqueous Solution Containing Sulfide and Sulfite over a ZnS–CuInS<sub>2</sub>–AgInS<sub>2</sub> Solid‐Solution Photocatalyst

Issei Tsuji, Hideki Kato, Akihiko Kudo

Angewandte Chemie International Edition · 2005 · 487 citations · 13 references

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Abstract

On the sunny side: A new photocatalyst effects hydrogen evolution from an aqueous solution containing S2− and SO32− ions. The photocatalyst is a Ru-loaded solid solution of ZnS–CuInS2–AgInS2 and works in visible light, e. g. under simulated solar irradiation (λ≥420 nm; see picture: CB conducting band, VB valence band).

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