Concepedia

[(η<sup>5</sup>‐C<sub>5</sub>Me<sub>5</sub>)CrO<sub>2</sub>]<sub>2</sub>—A Dinuclear Oxo‐Complex of Chromium(<scp>V</scp>)

Max Herberhold, Walter Kremnitz, Abbas Razavi, Helmut Schóllhorn, Ulf Thewalt

Angewandte Chemie International Edition in English · 1985 · 48 citations · 10 references

DOI

Concepts

Abstract

Lower and higher oxidation states of a metal are tolerated by cyclopentadienyl ligands. This is demonstrated by the oxidation of the nitrosyl complex 1 to 2, the first dinuclear oxo complex of chromium(V). The CrCr and CrO bonds in 2 are remarkably short.

References

10

Exhaustive Oxidative Decarbonylation of Metal Carbonyls by Light and Oxygen: The Example of (η<sup>5</sup>‐C<sub>5</sub>Me<sub>5</sub>)ReO<sub>3</sub>

Wolfgang A. Herrmann, Ricardo Serrano, Hans Bock · Angewandte Chemie International Edition in English · 1984 · 104 citations

, , +10

Preparation, properties and structures of the clusters hexakis(.mu.3-oxo)pentakis(.eta.5-cyclopentadienylvanadium), [(.eta.5-C5H5)5V5O6], and tetrakis(.mu.3-oxo)tetrakis(.eta.5-cyclopentadienylchromium), [(.eta.5-C5H5)4Cr4O4]

Frank Bottomley, Daniel E. Páez, Peter S. White · Journal of the American Chemical Society · 1982 · 82 citations

, , +15

(Pentamethylcyclopentadienyl)trioxorhenium, (.eta.5-C5Me5)ReO3

A. Hugo Klahn, Derek Sutton · Organometallics · 1984 · 76 citations

, , +6

Synthesis and structure of the distorted tetrahedral cluster [(.eta.5-C5H5)4Cr4O4], the third member of the [(.eta.5-C5H5)mMmOn] series where n and m satisfy Euler's theorem

Frank Bottomley, Daniel E. Páez, Peter S. White · Journal of the American Chemical Society · 1981 · 55 citations

, , +15

Chemistry of the Novel Oxo Half‐Sandwich Complex (η<sup>5</sup>‐C<sub>5</sub>Me<sub>5</sub>)ReO<sub>3</sub>: Functionalization and Aggregation

Wolfgang A. Herrmann, Ricardo Serrano, Ulrich Küsthardt et al. · Angewandte Chemie International Edition in English · 1984 · 53 citations

, , +14