Concepedia

Exhaustive Oxidative Decarbonylation of Metal Carbonyls by Light and Oxygen: The Example of (η<sup>5</sup>‐C<sub>5</sub>Me<sub>5</sub>)ReO<sub>3</sub>

Wolfgang A. Herrmann, Ricardo Serrano, Hans Bock

Angewandte Chemie International Edition in English · 1984 · 104 citations · 8 references

DOI

Concepts

Abstract

The trioxorhenium complex 3—lemon yellow, air-stable, crystalline—is surprisingly formed on photolysis of the tricarbonylrhenium complex 1 in THF. In complete absence of oxygen the initial product is 2, which (unlike analogous manganese complexes) is oxidized by air to 3.

References

8

Comprehensive Organometallic Chemistry

Chemical & Engineering News · 1982 · 2.3K citations · Full text

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Organometallic Photochemistry

Mark S. Wrighton, V. CARASSITI · Inorganica Chimica Acta · 1980 · 193 citations

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Methyltrioxorhenium. An air-stable compound containing a carbon-rhenium bond

I. R. Beattie, Peter J. Jones · Inorganic Chemistry · 1979 · 148 citations

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Coordination chemistry of the manganese and rhenium fragments (C5H5)M(CO)2

Kenneth G. Caulton · Coordination Chemistry Reviews · 1981 · 93 citations

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Effects of methyl group substitution on metal-coordinated cyclopentadienyl rings. Core and valence ionizations of methylated tricarbonyl(.eta.5-cyclopentadienyl)metal complexes

David C. Calabro, John L. Hubbard, Charles H. Blevins et al. · Journal of the American Chemical Society · 1981 · 79 citations

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