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Terminating catalytic asymmetric Heck cyclizations by stereoselective intramolecular capture of η3-allylpalladium intermediates: total synthesis of (−)-spirotryprostatin B and three stereoisomers

-Spirotryprostatin BEngineeringBiochemistryNatural SciencesTotal SynthesisOrganic ChemistryStereoselective SynthesisChemistryη3-Allylpalladium IntermediatesAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering