The Analyst · 1995 · 18 citations · 4 references
Natural SciencesBiochemistryChemistryAnalytical ChemistryPhysical ChemistrySpectroscopyAmino Acid ChemistryAmino Acid PropertiesFluorescence SpectroscopyPhotochemistryAbsorption SpectraAmino AcidsChemiluminescent MaterialsHückel Molecular Orbital TheoryIndole ChemistryIndole DerivativesMolecular Orbital Analysis
The chemiluminescent behaviour of some indole derivatives in alkaline solution in the presence of Fe3+ was studied in detail. The effects of various kinds of surfactants and oxidants on the chemiluminescent reaction were studied. A flow injection system with chemiluminescent detection was developed for the determination of tryptophan, and the effects of some inorganic ions and basic amino acids were examined. Based on the results of treatment with the Hückel molecular orbital method and the investigations of fluorescent and absorption spectra, the relationship between structural characteristics and chemiluminescent behaviour is discussed, and a possible mechanism for this chemiluminescent reaction is proposed.
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The Chemiluminescence of Indole Derivatives. I
Noboru Sugiyama, Masamoto Akutagawa, Taketoshi Gasha et al. · Bulletin of the Chemical Society of Japan · 1967 · 27 citations · Full text
Noboru Sugiyama, Hiroshi Yamamoto, Yoshimori Omote et al. · Bulletin of the Chemical Society of Japan · 1968 · 16 citations · Full text