Canadian Journal of Chemistry · 2005 · 40 citations · 16 references
Natural SciencesChemical EngineeringChemistryCatalysisReaction EngineeringThermal AnalysisMicrowave-assisted SynthesisMicrowave-assisted C-h FunctionalizationMicrowave-assisted CatalysisMicrowave-assisted Condensation ReactionsMicrowave-assisted Organic SynthesisReaction Kinetics Under Microwave Irradiation
Exposure of a variety of prochiral substrates to [(R)-()-DTBM-SEGPHOS]CuH + PMHS under microwave or conventionally heated conditions reduces reaction times for these hydrosilylations from hours to minutes without significant erosion in ee in most cases.Key words: asymmetric hydrosilylation, copper hydride, microwave irradiation.
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Solvias Josiphos Ligands: From Discovery to Technical Applications
Hans‐Ulrich Blaser, Walter Brieden, Benoı̂t Pugin et al. · Topics in Catalysis · 2002 · 331 citations