CuCl-Catalyzed Isomerization of gem-Chlorofluoro-Cyclopropanes into Chlorofluoroalkenes

Nikolai V. Volchkov, Maxim A. Novikov, M. B. Lipkind

Mendeleev Communications · 2013 · 15 citations · 18 references

Concepts

Abstract

CuCl-catalyzed isomerization of gem-chlorofluorocyclopropanes into chlorofluoroalkenes occurs as a result of the ring opening accompanied by the migration of chlorine atom. In the case of vinyl- or cyclopropyl-containing substrates, chlorofluoroalkadienes are formed.

References

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