Tropospheric Emission Spectrometer observations of the tropospheric HDO/H₂O ratio: Estimation approach and characterization

Abstract

We present global, vertical profile estimates of the HDO/H 2 O ratio from the Tropospheric Emission Spectrometer (TES) on the Earth Observing System (EOS) Aura satellite. We emphasize in this paper the estimation approach and error characterization, which are critical to determining the very small absolute concentration of HDO relative to H 2 O and its uncertainty. These estimates were made from TES nadir‐viewing (downlooking) thermal infrared spectral radiances observed on 20 September 2004. Profiles of HDO and H 2 O are simultaneously estimated from the observed radiances and a profile of the ratio is then calculated. This simultaneous, or “joint,” estimate is regularized with an a priori covariance matrix that includes expected correlations between HDO and H 2 O. This approach minimizes errors in the profile of the HDO/H 2 O ratio that are due to overlapping HDO and H 2 O spectroscopic lines. Under clear‐sky conditions in the tropics, TES estimates of the HDO/H 2 O ratio are sensitive to the distribution of the actual ratio between the surface and about 300 hPa with peak sensitivity at 700 hPa. The sensitivity decreases with latitude through its dependence on temperature and water amount. We estimate a precision of approximately 1% to 2% for the ratio of the HDO/H 2 O tropospheric densities; however, there is possibly a bias of approximately 5% in the ratio due to the HDO spectroscopic line strengths. These global observations clearly show increased isotopic depletion of water vapor at higher latitudes as well as increased depletion in the upper troposphere versus the lower troposphere.