Matrix-dependent cooperativity in spin crossover Fe(pyrazine)Pt(CN)4 nanoparticles

Abstract

Anisotropic nanoparticles of the Fe(pyrazine)Pt(CN)(4) network were prepared embedded in various matrices that revealed to have a dramatic effect on the cooperative spin crossover phenomena. By a judicious choice of the nature of the matrix and the control of interparticle distances, a hysteresis of 15 K was achieved close to room temperature for such nano-objects.