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In the title compound, (C(7)H(11)N(2))(2)[SnBr(5)Cl], there is Br/Cl disorder in 0.6561 (12):0.3439 (12) and 0.8438 (12):0.1561 (12) ratios over two of three halide sites in the centrosymmetric anion, such that an overall formulation of [SnBr(5)Cl](2-) arises. In the crystal, associations of two cations and one anion linked by N-H⋯Br hydrogen bonds occur.
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George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 2007 · 87.4K citations · Full text