Journal of the Chemical Society Perkin Transactions 2 · 1994 · 41 citations · 13 references
Natural SciencesChemistryMedicinal ChemistryAnalytical ChemistryOrganic ChemistrySpectroscopyChemical BondingCoordination ChemistryHeterocyclic ChemistryHeterocyclic CompoundsLigand BindingStructure-activity Relationship AnalysisHeterocyclic Medicinal ChemistryHeterocyclic ReactivityMacrocyclic CompoundsMacrocyclic LigandsMacrocyclic Receptors
The interaction of hydrogen ions with the series of macrocyclic receptors 2,5,8-triaza[9]paracyclophane, 2,6,10-triaza [11] paracyclophane, 13,14,16,17-tetramethyl-2,6,10-triaza[11]paracyclophane, 14,15,17,18-tetramethyl-2,5,8,11-tetraaza [12] paracyclophane and 16,17,19,20-tetramethyl-2,6,9,13-tetraaza[14]paracyclophane has been studied by potentiometry at 298.1 ± 0.1 K as well as by direct microcalorimetry and 1H and 13C NMR spectroscopy. Correlations of the basicity with the atomicity of the macrocycle, the type of chains within the bridge and the nature of the aromatic spacer are envisaged.
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