Chemical Science · 2014 · 86 citations · 78 references
Natural SciencesBiochemistryChemistryCatalysisStructure-activity RelationshipsSupramolecular ChemistryCatalytic MechanismsEnzyme KineticsEnzyme-substrate RecognitionHeterocyclic ChemistrySupramolecular CatalysisTerpenoid BiosynthesisCatalyst Structure - Activity RelationshipsProduct SelectivitySelectivityTerpene SynthasesTerpenoid Cyclization Mechanisms
, which numbers among the largest magnitudes of transition state stabilization measured with a synthetic host-catalyst. Host/guest size effects were observed to play an important role in host-mediated enantioselectivity.
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