Angewandte Chemie International Edition · 2010 · 29 citations · 19 references
Life SciencesBiochemistryChemistryBioorganic ChemistryCarbohydrate ChemistryNatural Product BiosynthesisCarbohydrate StructureGlycan BiosynthesisGlycan StructureGlycosidic Bond FormationN-linked GlycosylationProtein GlycosylationGlycan Structural AnalysisGlycopeptide SynthesisGlycoside SynthesisGlycosidic Bond Cleavage PathwaysGlycosidic Linkage PrecursorsGlycosylation Method DevelopmentNatural Product Total SynthesisTotal Synthesis-derived Analogues
The total synthesis of the tripeptide nominal banyaside B relies on nonstandard peptide-bond-forming reactions. A key outcome of these synthetic studies is the proposal of a revised structure for natural banyaside B, in which the glycoside is indeed linked to the Abn core at the axial C-9 OH and not C-7 as in nominal banyaside B.
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