Self‐Assembly of Perylene Monoimide Substituted Hexa‐<i>peri</i>‐hexabenzocoronenes: Dyads and Triads at Surfaces

Abstract

Nanoscale phase-segregated functional architectures can be formed both in monolayers at the solid/liquid interface and in the bulk by self-assembling electron-acceptor–electron-donor dyads and triads based on hexa-peri-hexabenzocoronene (HBC) and perylene monoimide (PMI). The figure shows charge transfer through the vertically segregated HBC and PMI channels in the bulk phase. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2089/2006/c2391_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.