Concepedia

X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes

E. J. Corey, Mark C. Noe, Sepehr Sarshar

Tetrahedron Letters · 1994 · 64 citations · 16 references

DOI

Concepts

References

16

The osmium-catalyzed asymmetric dihydroxylation: a new ligand class and a process improvement

K. Barry Sharpless, Willi M. Amberg, Youssef L. Bennani et al. · The Journal of Organic Chemistry · 1992 · 1.5K citations

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Asymmetric dihydroxylation via ligand-accelerated catalysis

Eric N. Jacobsen, István E. Markó, William S. Mungall et al. · Journal of the American Chemical Society · 1988 · 751 citations

, , +9

Conformational study of cinchona alkaloids. A combined NMR, molecular mechanics and x-ray approach

Gerard Dijkstra, Richard M. Kellogg, Hans Wynberg et al. · Journal of the American Chemical Society · 1989 · 272 citations

, , +9

New ligands double the scope of the catalytic asymmetric dihydroxylation of olefins

K. Barry Sharpless, Willi M. Amberg, Matthias Beller et al. · The Journal of Organic Chemistry · 1991 · 231 citations

, , +7

Enantioselective vicinal hydroxylation of terminal and E-1,2-disubstituted olefins by a chiral complex of osmium tetroxide. An effective controller system and a rational mechanistic model

E. J. Corey, Paul DaSilva Jardine, Scott C. Virgil et al. · Journal of the American Chemical Society · 1989 · 181 citations

, , +6