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Glory‐Scattering Measurement of Water–Noble‐Gas Interactions: The Birth of the Hydrogen Bond
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Citations
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References
2005
Year
Water–noble‐gas InteractionsEngineeringOh BondPhysicsNatural SciencesSpectroscopyChemical BondHydrogen BondAtomic PhysicsPhysical ChemistryMolecular Beam ScatteringComputational ChemistryQuantum ChemistryChemistryHydrogenProgressive Alignment
Incipient hydrogen bonds in water–noble gas complexes, which increase in strength from He to Xe, are manifested by progressive alignment along the OH bond (see picture) according to ab initio calculations. The strength of the interaction in excess of that expected for pure van der Waals forces was assessed experimentally by molecular beam scattering.
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