Full-Color OLEDs Integrated by Dry Dye Printing

Abstract

Dry dye printing and solvent-enhanced dye diffusion were used to locally dope a previously spin-coated poly(9-vinylcarbazole) (PVK) polymer film with different dyes to fabricate side-by-side red, green, and blue (RGB) organic light-emitting device pixels. The fabrication details and the resolution and stability of this patterning technique are discussed. The technique was then used to make combined polymer/small-molecule devices, in which the printability of polymer for color integration was combined with the superior transport properties and thin-layer capabilities of small molecules for high efficiency and low leakage current. To reduce reverse leakage current and raise efficiency, a blanket tris-8-hydroxyquinoline aluminum (Alq <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> ) electron transport layer was deposited on top of the polymer layer after the dye diffusion step, along with a 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline hole/exciton blocking layer between the Alq <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> and the PVK to ensure that all light emission occurred from the doped polymer and not from the Alq <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> . Devices with this hybrid doped polymer/small molecule structure have an extremely low reverse leakage current (with a rectification ratio of 10 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sup> at plusmn10 V). The electroluminescence efficiency of the devices was optimized by varying the dye concentration of the printing plate. A three-color passive-matrix test array with 300 mumtimes1 mm RGB subpixels was demonstrated with this structure