Efficiency Enhanced Colloidal Mn‐Doped Type II Core/Shell ZnSe/CdS Quantum Dot Sensitized Hybrid Solar Cells

Abstract

Colloidal Mn‐doped ZnSe/CdS core/shell quantum dots (QDs) are synthesized for the first time and employed as a strategy to boost the power conversion efficiency of quantum dot sensitized solar cells. By using Mn‐doping as a band gap engineering tool for core/shell QDs an effective improvement of absorption spectra could be obtained. The mid‐states generated by a proper Mn content alleviate carrier separation and enhance the electron injection rate, thus facilitating electron transport to the TiO 2 substrate. It is demonstrated that a device constructed with 0.25% Mn‐doped ZnSe/CdS leads to an enhancement of the electron injection rate and power conversion efficiency by 4 times and 1.3, respectively.