Concepedia

Asymmetric Synthesis of Functionalized Diarylmethanols Catalyzed by a New γ-Amino Thiol

Ping‐Yu Wu, Hsyueh‐Liang Wu, Biing‐Jiun Uang

The Journal of Organic Chemistry · 2005 · 70 citations · 15 references

DOI

Concepts

Abstract

[reaction: see text] A mild asymmetric arylation of aromatic aldehydes catalyzed by gamma-amino thiol 5 gave the corresponding diarylmethanols with 95 to >99.5% ee.

References

15

Catalyzed Asymmetric Aryl Transfer Reactions to Aldehydes with Boronic Acids as Aryl Source

Carsten Bolm, Jens Rudolph · Journal of the American Chemical Society · 2002 · 262 citations

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New 1,4-dihydropyridine derivatives with potent and long-lasting hypotensive effect.

Kanji Meguro, Masahiro Aizawa, Takashi Sohda et al. · Chemical and Pharmaceutical Bulletin · 1985 · 147 citations · Full text

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The MPEG Effect:  Improving Asymmetric Processes by Simple Additives

Jens Rudolph, Nina Hermanns, Carsten Bolm · The Journal of Organic Chemistry · 2004 · 120 citations

, , +12

Nucleophilic Displacement at Benzhydryl Centers:  Asymmetric Synthesis of 1,1-Diarylalkyl Derivatives

Yuri Bolshan, Cheng‐yi Chen, Jennifer R. Chilenski et al. · Organic Letters · 2003 · 73 citations

, , +14

Synthesis, absolute configuration and circular dichroism of some diarylmethane derivatives

Stephan Stanchev, Rosiza Rakovska, Nikolina Berova et al. · Tetrahedron Asymmetry · 1995 · 73 citations

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