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The influence of CT states and energy transfer on the luminescence of Ln2[Pt(CN)4]3⋅<i>y</i>H2O single crystals
29
Citations
11
References
1982
Year
Single CrystalsEngineeringExcitation Energy TransferChemistryLuminescence PropertyElectronic Excited StateSpectroscopic PropertyEmission MeasurementsPhotophysical PropertyInorganic ChemistryPhotochemistryPhysicsEnergy TransferOther TetracyanoplatinatesPhysical ChemistryCrystallographyExcited State PropertyNatural SciencesSpectroscopyApplied PhysicsCt States
Time resolved emission measurements of Ln2[Pt(CN)4]3⋅yH2O single crystals (LnCP) at T = 1.9 K are reported. The time dependence of the E⊥c polarized emission of these crystals—with the exception of LuCP—deviates considerably from that of other tetracyanoplatinates (MCP, M≠Ln). The results can be explained assuming an admixture of (Ln, 4f) orbitals to the emitting Pt-complex states (Pt, 5dz2).
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