Synthetic Communications · 2003 · 16 citations · 8 references
Natural SciencesChemistryCatalysisGreen ChemistryOrganic ChemistryCross-coupling ReactionsHeterocyclic ChemistryReaction Mechanisms1, 3-Dipolar CycloadditionCycloaddition ReactionsMicrowave HeatingMicrowave Irradiation EffectsMicrowave-assisted Organic SynthesisSolvent-free Cycloaddition Reactions
Abstract The reactivity of gem-dicyano epoxides with various alkenes is studies in solvent free conditions, and in homogeneous solution, under microwave irradiation. Microwave heating of these substrates in solvent, yields carbonyl ylides which give 1-3-dipolar cycloaddition. Keywords: Epoxides1,3-Dipolar cycloadditionMicrowave irradiationTetrahydrofuran derivatives Acknowledgments We wish to thank Pr. J. Hamelin, Université de Rennes I, France, for technical support and fruitful discussions.
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Stephen Caddick · Tetrahedron · 1995 · 1.4K citations
New Solvent-Free Organic Synthesis Using Focused Microwaves
André Loupy, Alain Petit, Jack Hamelin et al. · Synthesis · 1998 · 903 citations
1,3-Dipolar Cycloadditions of Pyridinium Dicyanomethylide under Microwave Irradiation
Angel D誕z-Ortiz, Enrique Dı́ez-Barra, A. Loupy et al. · Heterocycles · 1994 · 37 citations · Full text