Publication | Closed Access
Formation of Heterofullerenes by Direct Exposure of C<sub>60</sub> to Boron Vapor
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Citations
37
References
2012
Year
EngineeringClosed-shell SpeciesChemistryBoropheneBoron NitrideHexagonal Boron NitrideFullerenePristine CFormation RouteInorganic ChemistryPhysicsAtomic PhysicsPhysical ChemistryQuantum ChemistryBoron VaporDirect ExposureNatural SciencesApplied PhysicsCondensed Matter PhysicsMain Group ChemistryChemical Kinetics
Introducing boron: heterofullerenes that incorporate boron have been scarcely studied because a formation route from C(60) is not known. It is now reported that C(59)B(-), an electronically closed-shell species, is formed directly from pristine C(60) in the gas-phase by facile atom exchange reactions.
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